The DF shows a strong dependence on excitation energy, which is due to emission arising from higher energy excited dimeric states. In addition, the complex excited state nature of the polyspirobifluorene (PSBF) polymer is investigated in both dilute solutions and spin coated films. According to investigations carried out in dilute solutions steroid, solvent polarity and temperature dependent charge transfer (CT) state formation is observed as arising from the “inter/intrachain” interaction phenomena.

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